Carbon Nanotubes (CNT)

Nanotechnology

Nanotechnology refers broadly to a field of applied science and technology whose unifying theme is the control of matter on the atomic and molecular scale, normally 1 to 100 nanometers, and the fabrication of devices with critical dimensions that lie within that size range.

Run of Nanotechnology

• December 29, 1959: The first thought of Nanotechnology was given by Richard Feynman in "There's Plenty of Room at the Bottom" at an American Physical Society meeting at Caltech.
• September, 1981: First technical paper published on molecular nanotechnology. The same year scanning tunneling microscope (STM) invented.
• 1982-1990:Books and prizes on nanotechnology. Atomic force microscope invented in 1986.
• 1991: Carbon Nanotubes (CNT's) discovered.
• 1997: First company on nanotechnology founded, it's name is Zyvex.
• 1998-2007: Research, investment, conferences and meetings on nanotechnology.

Applications of Nanotechnology

It has or will have applications in almost all areas we can think of.

Applications in nanotechnology

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• Aerospace

• Space Elevators
• Spaceship
• Solar Sails
• Biorobots

• Medicine

• Identifying location of cancers cells. [1]
• Delivering chemotherapy drugs directly to cancer cells.[2]
• Nanoshells that concentrate the heat from infrared light to destroy cancer cells with minimal damage to surrounding healthy cells. [3]
• Nanotubes used in broken bones to provide a structure for new bone material to grow.[4]
• Nanoparticles that can attach to cells infected with various diseases and allow a lab to identify, in a blood sample, the particular disease.[5]

• Food Storage

• Clay nanocomposites are being used to provide an impermeable barrier to gasses such as oxygen or carbon dioxide in lightweight bottles, cartons and packaging films.
• Food storage bins are being produced with silver nanoparticles embedded in the plastic. The silver nanoparticles kill bacteria from any food that was previously stored in the bins, minimizing health risks from harmful bacteria.[6]
• It is possible to use nanosensors in plastic packaging to detect gases given off by food when it spoils. The packaging itself changes color to alert you to food gone bad.

• Agriculture

• Food will be more tastier and healthier using nanaotechnology.[7]
• Research is also being conducted to develop nanocapsules containing nutrients that would be released when nanosensors detect a vitamin deficiency in your body.
• Researchers are also working on pesticides encapsulated in nanoparticles; that only release pesticide within an insect’s stomach, minimizing the contamination of plants themselves.
• Another development being persued is a network of nanosensors and dispensers used throughout a food crop. The sensors recognize when a plant needs nutrients or water, before there is any sign that the plant is deficient. The dispensers then release fertilizer, nutrients, or water as needed, optimizing the growth of each plant in the field one by one.

• Chemistry

• Nanoparticles can be used as catalyst for chemical reactions.
• Nanotechnology can enable sensors to detect very small amounts of chemical vapors.[8]
• ZnO nanowires may lead to better chemical sensors, high-speed electronics.[9]
• Palladium nanoparticle hydrogen sensor.[10]

• Semiconductor devices

• NEMS
• OLED
• Memory chips
• Nanoemmissive display panel
• 45 nm wide transistor gates
• Magnetoresistive Random Access Memory (MRAM)
• Nanoscale integrated circuits

• Optics

• The first sunglasses using protective and antireflective ultrathin polymer coatings are on the market.
• Nanotechnology also offers scratch resistant surface coatings based on nanocomposites.
• Nano-optics could allow for an increase in precision of pupil repair and other types of laser eye surgery.

• Textile

• The use of engineered nanofibers already makes clothes water- and stain-repellent or wrinkle-free.
• Textiles with a nanotechnological finish can be washed less frequently and at lower temperatures.
• Nanotechnology has been used to integrate tiny carbon particles membrane and guarantee full-surface protection from electrostatic charges for the wearer.

• Consumer products

• Nanotechnology is now entered in almost all consumer products,for details see [11]

Number of products launched products launched vs categories

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3D model of three types of single-walled carbon nanotubes

Carbon Nanotubes (CNT's) are cylindrical shaped allotrope of carbon with length to diameter ratio exceeding 1,000,000.

Such cylindrical carbon molecules have novel properties that make them potentially useful in many applications in nanotechnology, electronics, optics and other fields of materials science. They exhibit extraordinary strength and unique electrical properties, and are efficient conductors of heat.

Types

Vectors representing orientation of three types of Single-walled CNT's

A Double-walled CNT formed by multiple Single-walled CNTs

1. Single-walled CNT's: This type of nanotube can be formed by rolling Graphene sheet. Graphene is a single planar sheet of sp²-bonded carbon atoms that are densely packed in a honeycomb crystal lattice. Types of Single-walled CNT's:
   • Zig-zag(n,0)
   • Armchair(n,n)
   • Chiral(2n,n)
2. Multi-walled: Multi-walled nanotubes(MWNT) consist of multiple layers of graphite rolled in on themselves to form a tube shape.
3. Fullerite: Fullerites are the solid-state manifestation of fullerenes and related compounds and materials. Being highly incompressible nanotube forms, polymerized single-walled nanotubes (P-SWNT) are a class of fullerites and are comparable to diamond in terms of hardness.
4. Torus: A nanotorus is a theoretically described carbon nanotube bent into a torus (doughnut shape).
5. Nanobud: The material fullerene-like "buds" are covalently bonded to the outer sidewalls of the underlying carbon nanotube. This hybrid material has useful properties of both fullerenes and carbon nanotubes.

Properties

• Physical Properties

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• Electrical Properties: Because of the symmetry and unique electronic structure of graphene, the structure of a nanotube strongly affects its electrical properties. For a given (n,m) nanotube, if n − m is a multiple of 3, then the nanotube is metallic, otherwise the nanotube is a semiconductor. Thus all armchair (n=m) nanotubes are metallic, and nanotubes (5,0), (6,4), (9,1), etc. are semiconducting. In theory, metallic nanotubes can have an electrical current density more than 1,000 times greater than metals such as silver and copper.

Method of fabrication

• Arc discharge: It is the simplest and most commonly used method of producing Carbon nanotubes. This method creates CNTs through arc-vaporization of two carbon rods placed end to end, separated by approximately 1mm, in an enclosure that is usually filled with inert gas (helium, argon) at low pressure (between 50 and 700 mbar).
• Laser ablation: In 1996, a dual-pulsed laser vaporization technique was developed, which produced SWNTs in gram quantities and yields of >70wt% purity. Samples were prepared by laser vaporization of graphite rods with a 50:50 catalyst mixture of Co and Ni (particle size ~1um) at 1200oC in flowing argon, followed by heat treatment in a vacuum at 1000oC to remove the C60 and other fullerenes.
• Chemical vapor deposition (CVD):Large amounts of CNTs can be formed by catalytic CVD of acetylene over Co and Fe catalysts supported on silica or zeolite.

• Polymer Composites: The first realized major commercial application of MWNTs is their use as electrically conducting components in polymer composites.Depending on the polymer matrix, conductivities of 0.01 to 0.1 S/cm can be obtained for 5% loading; much lower conductivity levels suffice for dissipating electrostatic charge. The low loading levels and the nanofiber morphology of the MWNTs allow electronic conductivity to be achieved while avoiding or minimizing degradation of other performance aspects, such as mechanical properties and the low melt flow viscosity needed for thin-wall molding applications.
• Electrochemical devices: Because of the high electrochemically accessible surface area of porous nanotube arrays, combined with their high electronic conductivity and useful mechanical properties, these materials are attractive as electrodes for devices that use electrochemical double-layer charge injection.
• Hydrogen storage: Nanotubes have been long heralded as potentially useful for hydrogen storage (for example, for fuel cells that power electric vehicles or laptop computers).
• Field emission devices: Industrial and academic research activity on electronic devices has focused principally on using SWNTs and MWNTs as field emission electron sources for flat panel displays, lamps, gas discharge tubes providing surge protection, and x-ray and microwave generators.
• Nanometer-sized electronic devices:
• Sensors and probes: Possible chemical sensor applications of nonmetallic nanotubes are interesting, because nanotube electronic transport and thermopower (voltages between junctions caused by interjunction temperature differences) are very sensitive to substances that affect the amount of injected charge.The main advantages are the minute size of the nanotube sensing element and the correspondingly small amount of material required for a response.

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Map categorization for CNT

• The Ajayan group is using carbon nanotubes as templates and molds for fabricating nanowires, composites, and novel ceramic fibers.[12]
• Dai group discovered how to grow nanotubes in specific directions and orientations on substrates using a chemical vapor deposition process.[13]
• Smalley group is developing methods of production, purification, derivitization, analysis, and assembly of nanotubes to solve real world problems. [14]
• Sun Research group is researching on polymeric nanocomposite materials based on carbon nanotubes and semiconductor and metal nanoparticles. [15]
• Accelerator Laboratory, the University of Helsinki is researching on Ion irradiation as a tool for studying and modifying properties of carbon nanotubes.[16]

• Number of patents filled on nanotubes are increasing exponentially by years.
• Last year i.e 2007, around 1450 patents are filled in this field.

IP Activity by year

• Major IPC classes with description is given.

Top IPC

• Hon Hai Prec Ind Co leads the number of patent filing by a great margin with their competitors.
• Samsung Electronics and Samsung SDI Co. Ltd. together contributes 148 patents.

Top Assignee

• Below is the link for sample spreadsheet analysis for Carbon nanotubes.

Sample analysis on carbon nanotubes

Dashboard Snapshots

Link to Dashboard

Dashboard for CNTs

IP Map

Map for electron emitter devices

IP Activity on carbon nanotubes in Electric discharge tubes and discharge lamps

IP activity by year

Top Assignee

Analysis

Sample Analysis on use of Carbon nanotubes in Electrical devices

Sample Analysis for discharge tubes and discharge lamps patents(30 patents)

Universities

• Universities play an important role in research and that's why it needs to be analyzed.
• Only 245 patents are filled by the universities research division.
• But companies are dependent on them for research activities.
• The analysis will give the insight of most involved university in terms of research on Carbon nanotubes.

Number of patents by universities in Carbon nanotubes area

Companies

• Large number of companies are now moving into this area.
• Number of startups are coming into the picture.

Nanotechnology market

• Nanotechnology is a growing market.
• Lux Research (a market research company in nanotechnology) believes that market will reach from $13 billion in 2005 to $292 billion in 2010.
• In 2015 market for nano materials will reach to $340 billion and electronics market will reach to $300 billion.
• US nanotech funding has increased from $270 million to $850 million.

Predictions of market by Lux research

US funding

Market by different categories

Carbon Nanotubes market

• Market size will increase from $6 million in 2004 to $1,070 million in 2014.

Carbon nanotubes market estimate

• Academic papers published on carbon nanotubes have been on the rise and patent filings have been keeping up with this upswing, says a review in the journal Science.
• According to the review, around 1,500 scientific papers were published in 2001 compared to about 1,100 in 2000 and around 700 in 1999.

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